5-Cyclohexyl-2-(2-fluorophenyl)-3-methylsulfinyl-1-benzofuran
نویسندگان
چکیده
In the title compound, C21H21FO2S, the cyclo-hexyl ring adopts a chair conformation. The 2-fluoro-benzene ring makes a dihedral angle of 38.68 (6)° with the mean plane [r.m.s. deviation = 0.018 (2) Å] of the benzo-furan fragment. In the crystal, mol-ecules are linked by pairs of C-H⋯O hydrogen bonds into dimers, which are further packed into stacks along the c axis by C-H⋯O hydrogen bonds. In addition, the stacked mol-ecules exhibit S⋯O contacts [3.1733 (13) Å] involving the sulfinyl groups. The F atom is disordered over two positions, with site-occupancy factors of 0.961 (3) and 0.039 (3).
منابع مشابه
5-Cyclohexyl-2-(3-fluorophenyl)-3-methylsulfinyl-1-benzofuran
In the title compound, C(21)H(21)FO(2)S, the cyclo-hexyl ring adopts a chair conformation. The 3-fluoro-phenyl ring makes a dihedral angle of 38.38 (6)° with the mean plane [r.m.s. deviation = 0.010 (1) Å] of the benzofuran fragment. In the crystal, mol-ecules are linked by weak C-H⋯O hydrogen bonds.
متن کامل5-Chloro-2-(2-fluorophenyl)-7-methyl-3-methylsulfinyl-1-benzofuran
In the title compound, C16H12ClFO2S, the dihedral angle between the mean planes of the benzo-furan and 2-fluoro-phenyl rings is 34.85 (6)°. In the crystal, mol-ecules are linked via pairs of C-H⋯O hydrogen bonds, forming zigzag chains along [001]. The chains are linked by C-H⋯π inter-actions, forming a three-dimensional structure.
متن کاملCrystal structure of 2-(3-fluorophenyl)-5-iodo-3-methylsulfinyl-1-benzofuran
In the title compound, C15H10FIO2S, the dihedral angle between the planes of the benzo-furan ring system [r.m.s. deviation = 0.015 (2) Å] and the 3-fluoro-phenyl ring is 29.63 (7)°. In the crystal, mol-ecules are linked into inversion dimers along the b-axis direction by two different pairs of C-H⋯O hydrogen bonds and I⋯O [3.228 (1) Å] contacts.
متن کامل5-Bromo-2-(2-fluorophenyl)-3-methylsulfinyl-1-benzofuran
In the title compound, C15H10BrFO2S, the 2-fluoro-phenyl ring makes a dihedral angle of 32.28 (6)° with the mean plane [r.m.s. deviation = 0.010 (1) Å] of the benzo-furan fragment. In the crystal, mol-ecules are linked by weak C-H⋯O hydrogen bonds and Br⋯O contacts [3.0917 (13) Å], forming a three-dimensional network.
متن کامل5-Cyclohexyl-2-(4-fluorophenyl)-3-methylsulfinyl-1-benzofuran
In the title compound, C(21)H(21)FO(2)S, the cyclo-hexyl ring adopts a classic chair conformation. The 4-fluoro-phenyl ring makes a dihedral angle of 31.05 (6)° with the mean plane of the benzofuran fragment. In the crystal, mol-ecules are linked through weak inter-molecular C-H⋯O and C-H⋯π inter-actions.
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عنوان ژورنال:
دوره 69 شماره
صفحات -
تاریخ انتشار 2013